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黄汉民
单位:化学与材料科学学院
地址:安徽省合肥市金寨路96号中国科学技术大学东区
邮编:230026
电话:86-551-63600752
个人主页: http://chem.ustc.edu.cn/szdw_16/bd/201603/t20160323_239246.html
实验室介绍:
 
个人简历 Personal resume
黄汉民,1974年6月生于湖北浠水,教授,博士生导师,英国皇家化学会会士(RSC-Fellow),中科院特聘研究员。2003年于中科院大连化学物理研究所获得有机化学博士学位,2004年至2008年在日本名古屋大学作JSPS博士后研究。2008年4月到2016年3月在中国科学院兰州化学物理研究所工作,先后任羰基合成与选择氧化国家重点实验室副主任和常务副主任。2016年3月调入中国科学技术大学化学系工作。作为第一作者或通讯作者已发表研究论文90多篇,其中JACS(8篇),ACIE(9篇),Chem.Rev(1篇)和Chem.Soc.Rev.(1篇),被引用3000多次。相关研究工作分别被Chemical & Engineering News、Nature Chemical Biology、Synform和Synfacts作为亮点评述。曾获国家自然科学基金优秀青年基金项目资助(2012),入选科技部中青年科技创新领军人才(2015),国家万人计划领军人才(2017),中国均相催化委员会均相催化青年奖(2013)和中科院优秀研究生指导教师奖(2015),指导的博士研究生多人次获得研究生国家奖和中科院院长奖,一人获得中科院优秀博士论文奖。目前主要研究领域为过渡金属催化的合成方法及应用研究,着重发展惰性C-H和C-N键活化新策略,在此基础上建立烃类物质和资源小分子高效转化的新反应。
 
研究方向 Research direction
1、金属有机化学
2、均相催化
3、不对称催化
 
招生信息 Enrollment information
对有机化学有强烈的兴趣,具备良好的金属有机化学基础知识背景。
 
论文专著 The monograph Researcher ID
1) Enantioselective Aminomethylamination of Conjugated Dienes with Aminals Enabled by Chiral Palladium Complex-Catalyzed C-N Bond Activation - J. Am. Chem. Soc. - 2016 - 2016, 138, 4314-4317.
2) Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation - J. Am. Chem. Soc. - 2015 - 2015, 137, 12490-12493.
3) Palladium-Catalyzed Dearomative Cyclocarbonylation via C-N Bond Activation - Angew. Chem. Int. Ed. - 2015 - 2015, 54, 10912-10916.
4) Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome Basicity-Barrier Imparted by Aliphatic Amines - Angew. Chem. Int. Ed. - 2015 - 2015, 54, 7657-7661.
5) Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN - Angew. Chem. Int. Ed. - 2015 - 2015, 54, 5900-5904.
6) alladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes via C-N Bond Activation - Angew. Chem. Int. Ed. - 2014 - 2014, 53, 7272-7276.
7) Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols - J. Am. Chem. Soc. - 2013 - 2013, 135, 18327-18330
8) An Efficient Rh/O2 Catalytic System for Oxidative C-H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen - J. Am. Chem. Soc. - - 2013, 135, 8850-8853.
9) Palladium-Catalyzed Oxidative Carbonylation of Benzylic C-H Bonds via Nondirected C(sp3)-H Activation. - J. Am. Chem. Soc. - - 2012, 134, 9902.
10) A Highly Diastereo- and Enantioselective Reaction for Constructing Functionalized Cyclohexanes: Six Contiguous Stereocenters in one Step - Angew. Chem. Int. Ed. - - 2012, 51, 1248-1251.
11) Enantioselective N-H Functionalization of Indole with α,β-Unsaturated γ-Lactams Catalyzed by Brønsted Acids - Angew. Chem. Int. Ed. - - 2011, 50, 5682-5686.
12) Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes to N-Sulfonyl Aldimines via C-H Bond Activation - J. Am. Chem. Soc. - - 2010, 132, 3650-3651.
13) Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy to Construct Allylamines. - J. Am. Chem. Soc. - - 2012, 134, 20613-20616.
14) Diastereo- and Enantioselective Catalytic Tandem Michael Addition/Mannich Reaction: Access to Chiral Isoindolinones and Azetidines with Multiple Stereocenters - Angew. Chem. Int. Ed. - - 2010, 49, 2728-2731.
15) Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp2N/sp3N hybrid Ligands R-BINAN-R΄-Py - J. Am. Chem. Soc. - - 2006, 128, 8716-8717.
16) Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C-H Bond Activation - Organometallics - 2016 - 2016
17) Transition-Metal Catalyzed Redox-Neutral and Redox-Green C−H Bond Functionalization - The Chemical Record - 2016 - 2016
18) Catalytic nucleophilic addition of alkynic C–H bond to α,β-unsaturated-γ-lactams - Chin. J. Catal. - 2016 - 2016
19) Copper-catalyzed decarboxylative cross-coupling of cinnamic acids and ACCN via single electron transfer - Org. Biomol. Chem. - 2016 - 2016, 14, 2399-2402.
20) Transition-Metal-Catalysed C-N Bond Activation - Chem. Soc. Rev. - 2016 - 2016, 45, 1257-1272.
21) Palladium-Catalysed Coupling Reaction of Aminals with N-Sulfonyl Hydrazones to Give Allylic Sulfones - Org. Chem. Front. - 2016 - 2016, 3, 259-267
22) Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines Promoted by Weak Acid - Tetrahedron Letters - 2016 - 2016, 57, 383-386.
23) Decarboxylative Alkylcarboxylation of α,β-unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling - Org. Lett. - 2015 - 2015, 17, 4968-4971.
24) Catalytic Nucleophilic Addition of Olefinic C-H Bond to α,β-Unsaturated-γ-Lactams - Tetrahedron Letters - 2015 - 2015, 57, 5533-5536.
25) Lewis acid-catalyzed Difunctionalization of Enol Ethers with Aminals and Alcohols to β-Amino Acetals - Journal of Molecular Catalysis (China) - 2015 - 2015, 29(2), 103-110.
26)  Copper-Catalyzed Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C-H Bonds - ACS Catal. - 2015 - 2015, 5, 2882-2885.
27) Transition-Metal-Catalyzed Direct Addition of Unactivated C−H Bonds to Polar Unsaturated Bonds - Chem. Rev. - 2015 - 2015, 115(9), 3468-3517.
28)  Diboron as Reductant for Nickel-Catalyzed Reductive Coupling: Rational Design and Mechanistic Studies - Chem. Comm. - 2015 - 2015, 51, 1850-1853.
29) Iron-Catalyzed Alkenylation of Isochroman Acetals with Simple Alkenes - ChemCatChem - 2015 - 2015, 7, 250-253.
30) Diastereo- and enantioselective conjugate addition of α-keto esters to nitroalkenes:Complete switch in the enantioselectivity by tuning the metal center or rigidity of the ligand - Chin. J. Catal. - 2015 - 2015, 36(1), 57-67.
31) Palladium-catalyzed carbonylation of allylamines via C−N bond activation leading to β,γ-unsaturated amides - RSC Adv. - 2014 - 2014, 4(109), 64235-64237.
32) Palladium-Catalyzed Direct Amination of Allylic Alcohols at Room Temperature - Synlett. - 2014 - 2014, 25(19), 2781-2786.
33) A water Promoted-PBM protocol for Synthesize Tertiary Amines with Arylboronic Acids, Paraformaldehyde and Secondary Amines - J. Molecular Catal. - 2014 - 2014, 28, 197.
34) Highly Enantioselective Hydrogenation of Steric Hindrance Enones Catalyzed by Ru-Complexes with Chiral Diamine and Achiral Phosphane - Org. Lett. - 2014 - 2014, 16, 3912-3915.
35) Palladium-Catalyzed Intramolecular Oxidative C−H Sulfuration of Aryl Thiocarbamates - Adv. Synth. Catal. - 2014 - 2014, 356. 11-12,2471-2476.
36) Rh-Catalyzed Oxidative C-H Activation/Annulation: Converting Anilines to Indoles with Molecular Oxygen as Sole Oxidant - Chem. Comm. - 2014 - 2014, 50, 4331-4334.
37) An Efficient Rh/O2 Catalytic System for Oxidative Heck Reaction of Indoles and Alkenes via C–H Functionalization - Adv. Synth. Catal. - 2014 - 2014, 356. 1509-1515.
38) Catalytic Cross Deoxygenative and Dehydrogenative Coupling of Aldehydes and Alkenes: Redox-Neutral Process to Skipped Dienes - Chem. Comm - - 2013, 49, 9839-9841.
39) Palladium-Catalyzed Oxidative Aminocarbonylation: A New Entry to Amides via C-H Activation - Org. Lett. - - 2013, 15, 3370-3373.
40) Copper-catalyzed oxidative amidation of dibenzylamines via C-H bond activation - Chin. J. Catal. - - 2013, 34(9), 1644-1650
41) Copper-Catalyzed Aerobic Oxidative Amination of Arylboronic Acid with Aminal under Base-Free Conditions - Tetrahedron Letters - - 2013, 54, 2713.
42)  A Ruthenium Catalyst with Simple Triphenylphosphane for Enantioselective Hydrogenation of Aromatic Ketones - ChemCatChem - - 2013, 5, 2253-2257
43) Cooperative Catalysis with Aldehyde and Copper: Development and Application in Aerobic Oxidative C-H Amination at Room Temperature. - Adv. Synth. Catal. - - 2013, 355, 1315.(Cover Pictur
44) Cu-Catalyzed Direct C-H Amination of 2-Alkylazaarenes with Azodicarboxylates via Nucleophilic Addition - Tetrahedron Letters - - 2013, 54, 711-714.
45) Lewis Acid-Catalyzed Conjugate Addition of sp3C-H Bonds to Ethylidene Malononitriles. - Adv. Synth. Catal. - - 2012, 354, 2146-2150.
46)  Brønsted Acid Enhanced Rhodium-Catalyzed Conjugate Addition of Aryl C-H Bonds to α,β-Unsaturated Ketones under Mild Conditions - Chem. Eur. J. - - 2012, 18, 9511-9515.
47)  Asymmetric Catalytic Carbon-Carbon Bond Coupling Reactions via C-H Bond Activation, - Catal. Sci. Technol. - - 2012, 2(6), 1099-1112.
48) Palladium-Catalyzed Selective C-H Benzylation towards Functionalized Azoles with Quaternary Carbon Center - Adv. Synth. Catal. - - 2012, 354, 1692-1700.
49) Stereoselective Synthesis of trans <beta>-Lactams via Palladium/N-Heterocyclic Carbene-Catalyzed Carbonylative [2+2] Cycloaddition - Tetrahedron Letters - - 2012, 53, 1613-1616.
50) Highly Diastereo- and Enantioselective Tandem Reaction toward Functionalized Pyrrolidines with Multiple Stereocenters - Org. Lett. - - 2011, 13, 5596-5599.
51) Chiral Phosphoric Acid Catalyzed Enantioselective Aza-Michael Addition of Aromatic Amines to Nitroolefins - Chin. J. Catal. - - 2011, 32, 1573-1576.
52) Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones - Chem. Eur. J. - - 2011, 17, 7760-7763.
53) Readily Available and Recoverable Chiral Ionic Phosphite Ligands for the Highly Enantioselective Hydrogenation of Functionalized Olefins - Tetrahedron: Asymmetry - - 2011, 22, 769-774.
54) Iron-Catalyzed Direct Alkenylation of 2-Substituted Azaarenes with N-Sulfonyl Aldimines via C-H Bond Activation - Org. Lett. - - 2011, 13, 2580-2583.
55) Copper-Catalyzed Oxidative Amination of Benzoxazoles via C-H and C-N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources - Org. Lett. - - 2011, 13, 522-525.
56) Asymmetric Diels-Alder reaction catalyzed by Chiral Cyclic diamines - Journal of Molecular Catalysis (China) - - 2011, 25, 6-10.
57) The Research Progress on the Grubbs-catalysts - Journal of Molecular Catalysis (China) - - 2011, 26, 566-575.
58) Lewis Acid-Catalyzed C-H Functionalization for Synthesis of Isoindolinones and Isoindolines - Adv. Synth. Catal. - - 2010, 352, 3195-3200.
59) Chiral Bronsted Acid Directed Iron-Catalyzed Enantioselective Friedel-Crafts Alkylation of Indoles with β-Aryl α’-Hydroxy Enones - Chem. Eur. J. - - 2010, 16, 1638-1645
60) An Efficient Synthesis of Chiral Diamines with Rigid Backbones: Application in Enantioselective Michael Addition of Malonates to Nitroalkenes - Org. Lett. - - 2009, 11, 4536.
61) Design and Synthesis of New Chiral Pyridine-Phosphite Ligands for the Copper-Catalyzed Enantioselective Conjugate Addition of Diethylzinc to Acyclic Enones - Tetrahedron: Asymmetry - - 2009, 20, 1425-1432
62) FeCl3-Catalyzed Addition of Et2Zn to Aldehydes - Journal of Molecular Catalysis (China) - - 2009, 23(6), 488-492.
63) Rhodium-Catalyzed enantioselective Hydrogenation of β-Phthalimide Acrylates to Synthesis of β2-Amino Acids - Org. Lett. - - 2006, 8, 3359-3362
64) Monophosphite Ligands Derived from Carbohydrates and H8-BINOL: Highly Enantioselective Rh-Catalyzed Asymmetric Hydrogenations - Tetrahedron: Asymmetry - - 2005, 16, 693-697.
65) Carbohydrate-Drived Monophosphite ligands for Rh-Catalyzed Enantioselective Hydrogenation of α- and β-Dehydroamino Acid Esters - Tetrahedron: Asymmetry - - 2004, 15, 2011-2019
66)  A Novel Class of P-O Monophosphite Ligands Derived from d-Mannitol: Broad Applications in Highly Enantioselective Rh-Catalyzed Hydrogenations - J. Org. Chem. - - 2004, 69, 2355-2361.
67) Structure Probing of D-Fructose Derived Ligands for Asymmetric Addition of Diethylzinc to Aldehydes - Tetrahedron: Asymmetry - - 2003, 14, 297-304
68) Readily available new pyridyl alcohols derived from D-glucose as ligands for the enantioselective addition of diethylzinc to aldehydes - Tetrahedron Letters - - 2003, 14, 1285-1289.
69)  Chiral Monophosphites Derived from Carbohydrate: Conformational Effect in Catalytic Asymmetric Hydrogenation - Org. Lett. - - 2003, 5, 4137-4139.
70)  Synthesis of 3,3&#900;-Diaryl-Substituted 2,2&#900;-Diamino-1,1&#900;-binaphthyl and Its Derivatives, - J. Org. Chem. - - 2010, 75, 4315-4318.
71)  Study on the synthesis and absolute configurations of novel chiral ligands derived from D-glucose by 2D NMR - Chinese Journal of Magnetic Resonance - - 2003, 20, 271-275.
72) Chiral organic catalysts and their applications in catalytic asymmetric reactions, Chinese Journal of Molecular Catalysis,2003, 17, 389-399. - - -
73) Synthesis of monodentate phosphite ligands derived from carbohydrates and H8-BINOL and their application in Rh-catalyzed asymmetric hydrogenation of &#61537;-dehydroamino acids. Chinese Journal of Molecular Catalysis, 2005, 19(5), 388-393. - - -
74) A novel synthesis of substituted phenylpyruvic acid by double carbonylation using cobalt pyridine-2-carboxylate catalyst. Synthetic Communications, 2000, 30, 3585-3588. - - -
75) Double carbonylation of benzyl chloride to substituted phenylpyruvic acid catalyzed by cobalt pyridine-2-carboxylate. Chemical Journal of Chinese Universities, 2000, 21, 286-288. - - -
76) Carbonylation of benzyl chloride to phenylacetic acid catalyzed by cobalt pyridine-2-carboxylate, Chinese Journal of fuel Chemistry and Technology, 2000, 28, 284-286. - - -
77) One pot formation of catalytic and double carbonylation of benzyl chloride, J. Mol. Cata. (A-Chemical), 2003, 193(1-2), 97-102. - - -
78) Five-membered Heterocycles, in Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis, Ed: Jean Rodriguez, and Damien Bonne, Wiley, 2015. - - -
79) Chiral phosphorous ligands derived from D-mannitol: synthesis and their applications in asymmetric catalysis, in Mannitol: Chemistry, Uses and Potential Side Effects, Nova Science Publishers Inc., 2013. - - -
80) Pd-Catalyzed Synthesis of Nitrogen-Containing Heterocycles, in Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation. Ed. Xiao-Feng Wu, Wiley-VCH 2016. - - -
 
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